Structural Consequences of Anionic Host−Cationic Guest Interactions in a Supramolecular Assembly
نویسندگان
چکیده
منابع مشابه
Post-assembly guest oxidation in a metallo-supramolecular host and structural rearrangement to a coordination polymer.
PTA hosted in a copper metallo-supramolecular triangle undergoes post-assembly oxidation to form PTAO in aerated solutions. The oxidation is triggered by selected co-solvents that also govern the formation of the final crystalline product leading to a discrete host-guest triangle {PTAO@[Cu(o-L)]3} or to a 1D coordination polymer {(PTAO)2@[Cu8][Cu2]}∞ containing a {Cu8} ring with a double hostin...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2008
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic8012848